Many countries are trying to overcome global warming due to greenhouse gas emissions, such as CO₂. In particular, the regulation on CO₂ emissions of internal combustion engine vehicles has become strictly important. Thus, the automobile companies are putting more effort for improving the manufacturing of the battery, which is the main power supply of electrical vehicles. In the electrode cutting process, laser cutting has been actively discussed to solve problems originating from the conventional electrode cutting processes. However, there is a lack of research considering the effect of thickness of the active material on laser cutting. In this paper, the effect of thickness of the active material on laser cutting of electrodes is analyzed. First, the cut electrodes are observed through a scanning electron microscope (SEM). Next, the kerf width and clearance width of the electrodes are measured and compared at the same laser parameter. The kerf width and clearance width of relatively thick electrodes are narrowly formed. Finally, the cutting quality of the electrode is compared. A uniform cut edge is observed as the scanning speed increases.