The need for large-area cross-sectional analysis with nanometer precision is rapidly growing in various advanced manufacturing sectors. Traditional focused ion beam (FIB) techniques are too slow for milling millimeter-scale volumes. They often introduce ion implantation, redeposition, and curtaining effect, which ultimately prevent effective large-area processing and analysis. To overcome these limitations, we developed a hybrid machining process integrating femtosecond laser micromachining for rapid roughing with FIB milling for precision finishing. Angle of incidence (AOI) control during laser machining was employed to minimize the taper angle of laser-ablated sidewalls, thereby significantly reducing subsequent FIB milling volume. Using a 1030 nm, 350 fs laser, we achieved nearly vertical sidewalls (taper angle: ~2.5° vs. ~28° without AOI control) in silicon. Raman spectroscopy revealed a laser-affected zone extending about 2 μm perpendicular to the sidewall, indicating the need for further FIB milling besides laser-tapered regions to remove laser-induced damage. On multilayer ceramic capacitors and micropillar fabrication, the hybrid laser-FIB method achieved efficient large-area cross sections with preserved microscale details. We present the development of an integrated triple-beam system combining laser, plasma FIB, and SEM, capable of fast volume removal and nanoscale imaging in one equipment. This approach can markedly improve throughput for large-area cross-sectional analysis.

In a pilot natural super-hydrophobic surfaces study, a super-hydrophobic surface was made by coating, etching, laser ablation, chemical vapor deposition and lithography. In this study, cone-shaped periodic micro and nano-structures were constructed on a silica surface with femtosecond and picosecond laser, and the period of micro-structures between cone shape patterns was increased with 10 μm intervals. The contact angle and image of the super-hydrophobic surface were analysed and the cone (Aspect-ratio 1.27) shape model with micro-protrusion structure similar to the surface of the lotus leaf was made to measure the contact angle. To analyse the differences in the contact angles between the cone shapes and heights of the micro-protrusion, different samples with cone (Aspect-ratio 1.27), sphere (Aspect-ratio 1.00) shapes were made through laser micro-machining technology. To mimick the natural lotus leaves, the optimum condition was a cone shape. Samples of PDMS with different shapes and mixed micro/nano-structures were fabricated with a PDMS mold insert. The largest contact angle was measured at 170.42° which is similar to the contact angle of the lotus leaf. This mold insert could be used repeatedly. The molding process is advantageous for large areas and mass production.