The ionomer content in the catalyst layer is a crucial design factor that affects the performance of polymer electrolyte membrane fuel cells (PEMFCs). However, the optimal ionomer content can vary based on the surrounding humidity levels. This study systematically evaluated the influence of the ionomer-to-carbon (I/C) ratio (0.00, 0.55, and 0.91) on PEMFC performance under fully humidified (RH 100%) and low-humidity (RH 25%) conditions. Membrane-electrode assemblies (MEAs) were fabricated using a spray coating technique, and their electrochemical properties were analyzed through polarization curves and electrochemical impedance spectroscopy (EIS). Under RH 100%, the MEA with an I/C ratio of 0.55 achieved the highest peak power density of 519.8 mW/cm², indicating a successful balance between proton conductivity and gas transport. Conversely, under RH 25%, the best performance of 203.9 mW/cm² was observed at an I/C ratio of 0.91. This shift is attributed to improved water retention at higher ionomer content, which reduced membrane dehydration and lowered both ohmic and Faradaic resistances. These findings highlight the dual role of the ionomer in facilitating proton transport and managing water balance, emphasizing the necessity of optimizing the I/C ratio according to operating conditions for stable and high-performing PEMFC operation.

To reduce the use of fossil fuels, the adoption of battery electric vehicles (BEVs) using lithium-ion batteries has been increasing in internal combustion engine alternatives. Accordingly, significant efforts have been made to improve the manufacturing process of lithium-ion batteries within electric vehicles. In particular, the cutting process of lithium-ion batteries has been actively discussed as it is closely related to battery performance. Laser-based cutting enables a more precise and sustainable manufacturing process. The laser ablation threshold has been investigated in many studies to achieve high-precision laser processing. While laser parameters and ambient conditions have been examined to determine the laser ablation threshold, studies focusing on the effect of relative humidity remain insufficient. Thus, this study investigated the laser ablation threshold of aluminum foil under varying relative humidity conditions. First, a laser interaction chamber was fabricated to control the relative humidity during experiments. A scanning electron microscope (SEM) was then used to observe laser ablation craters and analyze the threshold. The variation of the laser ablation threshold with relative humidity revealed changes in the interaction between the laser and aluminum foil depending on the humidity level.