In this study, a highly sensitive analysis device for hydrogen sulfide that could be used quickly and easily on site was developed using a colorimetric paper sensor. To optimize analysis conditions, tests were performed for each function. Performances of the method using laboratory equipment and tools and the method using the developed device for hydrogen sulfide analysis were compared. The trend line of changes in parameter b of the image acquired by the on-site analytical device for hydrogen sulfide was calculated as y = 0.517x - 0.141 with a coefficient of determination (R2) of 0.9874. It was comparable to the method performed at the laboratory level, showing an excellent linearity. Using the calculated trend line as a calibration curve, the detection limit and quantification limit were found to be 2.386 μM and 7.952 μM, respectively. A reproducibility test showed a relative standard deviation of 5.7%, indicating a low dispersion of results.

A novel method for the development of a highly sensitive triboelectric sensor based on porous PDMS matrix and carbon black (CB) particles is proposed. The porosity of the PDMS is controlled by using wet sugar particle sizes, and we fabricate a porous PDMS plate with a pore-to-volume ratio of 46%, which has a larger internal contact area compared to a non-pore one. To investigate the sensitive responses of the sensor, two key processes for the deposition of CB particles are conducted. One is the stirring process and another is ultrasonic vibration waving process. Based on the proposed method, a high-performance flat triboelectric sensor is fabricated. By a weight drop test of two different sensors, the amount of out-voltage is changed to approximately 29.1 and 95.1%, respectively. Through this study, we can evaluate that the sensitivity of triboelectric sensors is affected by the deposition method of the CB particles. The proposed flexible triboelectric sensor can be applied to analyze human physical behavior. Also, we believe that it can be applied to measure various physical signals such as contact force or gripping force with small values.