Directed energy deposition (DED) enables the efficient fabrication and repair of large metal components. However, repeated reuse of the powder generates degraded particles, which must be removed by sieving. This study used scanning electron microscopy and laser diffraction particle size analysis to characterize the sieve-rejected Inconel Alloy 939 powder collected sequentially after each of four DED processing cycles (R1–R4). The rejected powder consistently contained elongated, irregular, and satellite-attached particles, and its particle size increased progressively with each reuse cycle. The mean particle size increased by 16.8%, from 51.1 μm for R1 to 59.7 μm for R4. The D₁₀, D₅₀, and D₉₀ values also increased, with D90, for example, rising from 71.5 to 82.2 μm. These results suggest that sieving may serve as an important quality control step for maintaining powder quality when the powder is repeatedly reused in DED.